Schrödinger equation
$$ i\hbar\frac{\partial \psi}{\partial t}
= \frac{-\hbar^2}{2m} \left(
\frac{\partial^2}{\partial x^2}
+ \frac{\partial^2}{\partial y^2}
+ \frac{\partial^2}{\partial z^2}
\right) \psi + V \psi.$$
Hessian matrix (Hessian)
$$ H = \begin{bmatrix}
\dfrac{\partial^2 f}{\partial x_1^2} & \dfrac{\partial^2 f}{\partial x_1\,\partial x_2} & \cdots & \dfrac{\partial^2 f}{\partial x_1\,\partial x_n} \[2.2ex]
\dfrac{\partial^2 f}{\partial x_2\,\partial x_1} & \dfrac{\partial^2 f}{\partial x_2^2} & \cdots & \dfrac{\partial^2 f}{\partial x_2\,\partial x_n} \[2.2ex]
\vdots & \vdots & \ddots & \vdots \[2.2ex]
\dfrac{\partial^2 f}{\partial x_n\,\partial x_1} & \dfrac{\partial^2 f}{\partial x_n\,\partial x_2} & \cdots & \dfrac{\partial^2 f}{\partial x_n^2}
\end{bmatrix} $$